Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from l-phenylalanine† †Electronic supplementary information (ESI) available: CCDC 1051429 and 1051473. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00731c

Enantioselective annulation of enals with 2-naphthols by triazolium salts derived from l-phenylalanine.

A series of chiral triazolium salts have been synthesized from methyl l-phenylalaninate hydrochloride. The NHCs derived from this class of novel triazolium salts were found to be highly efficient catalysts in the annulation reaction of enals and 2-naphthols. These reactions proceeded with high chemoselectivity and wide substrate scope affording enantioenriched β-arylsplitomicins in good yields ...

N-Heterocyclic carbene-catalyzed oxidative [3 + 2] annulation of dioxindoles and enals: cross coupling of homoenolate and enolate† †Electronic supplementary information (ESI) available: Experimental procedures and compound characterizations (PDF). CCDC 1041425 (3fb). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc04135c Click here for additional data file. Click here for additional data file.

Beijing National Laboratory for Molecular S Recognition and Function, Institute of Chemi 100190, China. E-mail: [email protected] Marine College, Shandong University at We 264209, China. E-mail: [email protected] University of Chinese Academy of Sciences, † Electronic supplementary information ( and compound characterizations (PDF) crystallographic data in CIF or o 10.1039/c6sc04135c ‡ X.-Y. C...

Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives† †Electronic supplementary information (ESI) available. CCDC 1536822. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc02809a Click here for additional data file. Click here for additional data file.

Combining silver- and organocatalysis: an enantioselective sequential catalytic approach towards pyrano-annulated pyrazoles† †Electronic supplementary information (ESI) available. CCDC 1035443. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c4cc09495f

Organocatalytic asymmetric chlorinative dearomatization of naphthols† †Electronic supplementary information (ESI) available: Experimental procedures and analysis data for the new compounds. CCDC 1048128 ((R)-2t) and 1048302 ((R)-2d). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00494b